Low-temperature Structures and Raman Spectra of Crystalline Modifications of Selenium Difluoride Dioxide.
| Authors | |
|---|---|
| Year of publication | 1995 |
| Type | Article in Periodical |
| Magazine / Source | J. Chem. Soc. Dalton Trans. |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Selenium difluoride dioxide; Low-temperature Structures; Raman spectra; Factor-group analysis |
| Description | The existence of two crystalline modifications of selenium difluoride dioxide between 174 and 100 K,indicated by low-temperature Raman spectra of solid SeO2F2, has been revealed by single-crystal X-ray diffraction techniques at 150 and 120 K. Raman spectra of both modifications are consistent with their crystal structures and a factor-group correlation analysis confirmed the observed splittings of the Se-F stretching modes. |
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