Synthesis and Chemical Properties of Halogenophosphates

Warning

This publication doesn't include Faculty of Arts. It includes Faculty of Science. Official publication website can be found on muni.cz.

Authors	SLUKA Radek ČERNÍK Miloš
Year of publication	2002
Type	Article in Proceedings
Conference	Sborník příspěvků IV. seminář Pokroky v anorganické chemii
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	Diphosphoryl tetrafluoride; dichlorophosphate; chlorofluorophosphate; 1;1-difluoro-2-chlorodiphosphate; 1;1;2-trifluorodiphosphate; 1;1;3;3-tetrafluorotriphosphate
Description	The systematic study of the synthetic methods and structures of halogenophosphates enabled the succesfull preparations of tetraphenylphosphonium dichlorophosphate and 1,1,3,3-tetrafluorotriphosphate,which constitution was confirmed by X-ray crystal structure analysis.In addition,also the pure solid PPh4[PO2ClF] was isolated and the formation of 1,1,2-trifluorodiphosphate and 1,1,-difluoro-2-chlorodiphosphate could be revealed by 19F and 31P NMR spectroscopy.
Related projects:	Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles