Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates

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Authors

HAVEL Václav SADILOVÁ Tereza ŠINDELÁŘ Vladimír

Year of publication 2018
Type Article in Periodical
Magazine / Source ACS Omega
MU Faculty or unit

Faculty of Science

Citation
Web https://pubs.acs.org/doi/10.1021/acsomega.8b00497
Doi http://dx.doi.org/10.1021/acsomega.8b00497
Keywords INHIBITORS; BINDING; ANIONS
Description A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle.
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